Blocky cationic organopolysiloxane

ABSTRACT

Disclosed herein are inventive blocky cationic organopolysiloxanes and consumer product compositions comprising such organopolysiloxanes. Such compositions can deposit effectively onto target substrates to deliver consumer-desired benefits such as conditioning, anti-wrinkle, softness, and anti-static.

FIELD OF THE INVENTION

The present invention relates to inventive blocky cationicorganopolysiloxane compounds. It also relates to consumer productcompositions comprising the inventive compounds and to methods of makingand use.

BACKGROUND OF THE INVENTION

Cationic conditioning polymers meant for deposition onto negativelycharged surfaces, such as fabric, skin, or hair, are included in manycommon consumer product compositions. Such products can provideconsumer-desired benefits such as softness, lubricity, hand,anti-wrinkle, hair conditioning, frizz control, skin moisturization, andcolor protection. The effectiveness of any particular conditioningpolymer depends not only upon the chemical and physical properties ofthe conditioning polymer itself, but also upon those of the targetedsurface and the product formulation in which the conditioning polymer isdelivered.

Many consumer products containing cationic conditioning polymers are inthe form of aqueous-based rinse-off compositions, such as hair shampoos,body washes, laundry detergents, and fabric softeners. Despite thepopularity of these rinse-off compositions, such product formsfrequently experience difficulties effectively depositing these cationicconditioning polymers, which are typically hydrophobic, onto the targetsurfaces. Incorporating these conditioners into aqueous-based productsoften results in the conditioner being preferentially rinsed away fromthe intended site of deposition, rather than effectively deposited. Thisproblem is particularly pronounced in the context of cleansingcompositions containing surfactant, especially those containing anionicsurfactant.

Anionic surfactants can interfere with deposition by formingcomplexes/precipitates with the cationic conditioning polymers. Thehigher the concentration of anionic surfactant, the more difficult itbecomes to deposit cationic benefit actives. This leads tonon-cost-effective use and waste of materials. Further, even if anacceptable level of deposition is attained, these formulations may lackshelf-stability due to flocculation and precipitation, making themunacceptable as consumer products.

Several materials exist in the art, but are not wholly satisfactory. Forexample, the material described by Ono (WO 99/32539) comprisesfunctionalized end groups having heteroatoms such as oxygen, nitrogen,sulfur, or halogens. These functionalized end groups can lead toundesirable reactions that pose stability issues for compositionscomprising these materials. For instance, Ono's silicones can reactfurther through these end groups, leading to further condensation and/orpolymerization of the silicones in the compositions during storage.

Also known in the art are quaternized silicones that include alkyleneoxide units, such as those described by Masschelein (U.S. Pat. No.6,903,061). The quaternized silicones described by Masschelein may betoo water soluble for a given application, and thus can have a reducedcapacity as conditioning polymers, since these materials tend topartition into water at a higher than desired level rather than depositon the target substrate. Further, when these materials are used as theconditioning active, they can have an undesirable feel because of theirhigh permeability to water and water vapor. Additionally, because of thepotential for variability in the alkylene oxide moiety, these materialscan be difficult to formulate reproducibly. This can limit the desireddegree of functionality in a silicone material. It would desirable tohave a material the provides greater flexibility via the level ofquaternization. Similarly, the ethoxylated quaternized siliconematerials disclosed by Boutique (U.S. Pat. No. 6,833,344) suffer frommany of the same inadequacies of those described by Masschelein.

There is still a need to provide cationic conditioning polymers that aresuitable for use in a wide range of consumer product applications. Thepresent invention provides cationic conditioning polymers and consumerproduct compositions comprising conditioning polymers that caneffectively deposit and provide conditioning benefits to negativelycharged substrates while avoiding the aforementioned disadvantages.

SUMMARY OF THE INVENTION

The present invention attempts to solve one or more of theaforementioned needs by providing, in one aspect, inventive blockycationic organopolysiloxanes that are suitable for use in a wide rangeof consumer product compositions. The inventive compounds arefunctionalized to favorably interact with the targeted substrate andproduct composition to deliver desired deposition and conditioningbenefits, as well as desired shelf-stability.

Without being bound by theory, when cationic charge that could otherwisefacilitate hydrophobic benefit agent deposition is randomly distributedalong the length of the benefit agent polymer, the charge can be toohighly dispersed to adequately facilitate deposition. The inventivepolymer's charge density can be custom-tailored (e.g., higher chargedensity) to enhance deposition and conditioning performance in differentuse environments. Further, by varying the inventive polymer's level ofhydrophobic substitution and/or the degree of ethoxylation,propoxylation, and alkoxylation, the inventive polymer can be formulatedinto a desirably stable composition for a variety of use environments.By controlling charge density and hydrophobic substitution and/or degreeof ethoxylation, propoxylation, and more generally alkoxylation, theinventive compounds can be custom-tailored for a variety of productformulations and uses.

The current invention further solves the aforementioned needs byproviding blocky cationic organosiloxanes comprised of multiple blocksof cationic portions and un-charged silicone portions as components ofthe same organopolysiloxane polymer. Without being bound by theory it isfelt that these multi-block organopolysiloxanes offered a preferablesolution to the aforementioned needs in that any of the multiplecationic portions of the organopolysiloxane can form a first interactionwith the target surface, thereby facilitating the further adherence ofsubsequent cationic portions of the same molecule with the targetsurface, and that as such, the overall deposition of theorganopolysolixane on the target surface is enhanced.

DETAILED DESCRIPTION OF THE INVENTION I. Definitions

As used herein, the “blocky cationic organopolysiloxane” may also bereferred to as the “organopolysiloxane”.

As used herein “consumer product” means baby care, personal care, fabric& home care, family care (e.g., facial tissues, paper towels), femininecare, health care, beauty care and like products generally intended tobe used or consumed in the form in which they are sold. Such productsinclude but are not limited to diapers, bibs, and wipes; products forand/or methods relating to treating hair (human, dog, and/or cat),including, bleaching, coloring, dyeing, conditioning, shampooing,styling; deodorants and antiperspirants; personal cleansing; cosmetics;skin care including application of creams, lotions, and other topicallyapplied products for consumer use including fine fragrances; and shavingproducts, products for and/or methods relating to treating fabrics, hardsurfaces and any other surfaces in the area of fabric and home care,including: air care including air fresheners and scent delivery systems,car care, dishwashing, fabric conditioning (including softening and/orfreshening), laundry detergency, laundry and rinse additive and/or care,hard surface cleaning and/or treatment including floor and toilet bowlcleaners, and other cleaning for consumer or institutional use; productsand/or methods relating to bath tissue, facial tissue, paperhandkerchiefs, and/or paper towels; tampons, feminine napkins; productsand/or methods relating to oral care including toothpastes, tooth gels,tooth rinses, denture adhesives, and tooth whitening.

As used herein, the term “cleansing and/or treatment composition” is asubset of consumer products that includes, unless otherwise indicated,personal care, fabric care, and home care products. Such productsinclude, but are not limited to, products for treating hair (human, dog,and/or cat), including, bleaching, coloring, dyeing, conditioning,shampooing, styling; deodorants and antiperspirants; personal cleansing;cosmetics; skin care including application of creams, lotions, and othertopically applied products for consumer use including fine fragrances;and shaving products, products for treating fabrics, hard surfaces andany other surfaces in the area of fabric and home care, including: aircare including air fresheners and scent delivery systems, car care,dishwashing, fabric conditioning (including softening and/orfreshening), laundry detergency, laundry and rinse additive and/or care,hard surface cleaning and/or treatment including floor and toilet bowlcleaners, granular or powder-form all-purpose or “heavy-duty” washingagents, especially cleaning detergents; liquid, gel or paste-formall-purpose washing agents, especially the so-called heavy-duty liquidtypes; liquid fine-fabric detergents; hand dishwashing agents or lightduty dishwashing agents, especially those of the high-foaming type;machine dishwashing agents, including the various tablet, granular,liquid and rinse-aid types for household and institutional use; liquidcleaning and disinfecting agents, including antibacterial hand-washtypes, cleaning bars, mouthwashes, denture cleaners, dentifrice, car orcarpet shampoos, bathroom cleaners including toilet bowl cleaners; hairshampoos and hair-rinses; shower gels, fine fragrances and foam bathsand metal cleaners; as well as cleaning auxiliaries such as bleachadditives and “stain-stick” or pre-treat types, substrate-laden productssuch as dryer added sheets, dry and wetted wipes and pads, nonwovensubstrates, and sponges; as well as sprays and mists all for consumeror/and institutional use; and/or methods relating to oral care includingtoothpastes, tooth gels, tooth rinses, denture adhesives, toothwhitening. The care agents can advantageously be used in householdpolishes and cleaners for floors and countertops to provide benefitssuch as enhanced shine. Care agents in fabric softeners can helppreserve “newness” because of their softening properties, and thosehaving elasticity can help smooth out wrinkles. The care agents can alsoenhance shoe cleaning and polishing products.

As used herein, the term “personal care cleansing and/or treatmentcomposition” is a subset of cleaning and treatment compositions thatincludes, unless otherwise indicated, products for treating hair,including, bleaching, coloring, dyeing, conditioning, shampooing,styling; deodorants and antiperspirants; personal cleansing; cosmetics;skin care including application of creams, lotions, and other topicallyapplied products for consumer use including fine fragrances; and shavingproducts; liquid cleaning and disinfecting agents includingantibacterial hand-wash types, cleaning bars, mouthwashes, denturecleaners, and dentifrice cleaners; hair shampoos and hair-rinses; showergels, fine fragrances, and foam baths; substrate-laden products such asdry and wetted wipes and pads, nonwoven substrates, and sponges; as wellas sprays and mists all for consumer or/and institutional use; and/ormethods relating to oral care including toothpastes, tooth gels, toothrinses, denture adhesives, and tooth whitening.

As used herein, the term “fabric and/or hard surface cleansing and/ortreatment composition” is a subset of cleaning and treatmentcompositions that includes, unless otherwise indicated, granular orpowder-form all-purpose or “heavy-duty” washing agents, especiallycleaning detergents; liquid, gel or paste-form all-purpose washingagents, especially the so-called heavy-duty liquid types; liquidfine-fabric detergents; hand dishwashing agents or light dutydishwashing agents, especially those of the high-foaming type; machinedishwashing agents, including the various tablet, granular, liquid andrinse-aid types for household and institutional use; liquid cleaning anddisinfecting agents, including antibacterial hand-wash types, cleaningbars, car or carpet shampoos, bathroom cleaners including toilet bowlcleaners; and metal cleaners, fabric conditioning products includingsoftening and/or freshening that may be in liquid, solid and/or dryersheet form; as well as cleaning auxiliaries such as bleach additives and“stain-stick” or pre-treat types, substrate-laden products such as dryeradded sheets, dry and wetted wipes and pads, nonwoven substrates, andsponges; as well as sprays and mists. All of such products, asapplicable, may be in standard, concentrated or even highly concentratedform even to the extent that such products may in certain aspects benon-aqueous.

As used herein, articles such as “a” and “an” are understood to mean oneor more of what is claimed or described.

As used herein, the terms “include”, “contain”, and “have” arenon-limiting and do not exclude other components or features beyondthose expressly identified in the description or claims.

As used herein, the terms “treatment agent”, “benefit agent”, “active”,“active agent”, and/or “care agent” and the like are usedinterchangeably to mean materials that can impart desirable aestheticand/or functional properties (e.g., conditioning benefits such assoftening or freshening) to a substrate. For example, the inventiveorganopolysiloxane polymer of the present invention can be used as aconditioning agent to impart conditioning benefits to substrates.

As used herein, the terms “conditioning agent” and “conditioning aid”are used interchangeably to refer to a material that delivers desirableconditioning effects (e.g., benefits such as softening or freshening) toa substrate. Conditioning agents are a type of treatment agent.

As used herein, the term “conditioning polymer” means a polymer thatdelivers desirable conditioning effects (e.g., softening or freshening)to a substrate.

As used herein, the term “substrate” is synonymous and usedinterchangeably with the terms “situs” and “surface”. Non-limitingexamples of substrates include paper products, fabrics, garments, hardsurfaces, hair, and skin.

As used herein, “targeted substrate” means a substrate, or the relevantportion of a substrate, upon which deposition is intended.

As used herein, a “deposition aid” is a material that assists anothermaterial (e.g., a benefit agent) to deposit (e.g., adhere) to a targetedsubstrate. The term “deposition aid” is broad enough to encompass bothpolymeric deposition aids (i.e. “deposition polymer”) and non-polymericdeposition aids.

As used herein, “adjunct” means an optional material that can be addedto a composition to complement the aesthetic and/or functionalproperties of the composition.

As used herein, “auxiliary composition” refers to one or morecompositions that when combined with a benefit agent emulsion of thepresent invention, form a consumer product composition. The auxiliarycomposition may be in the form of one or more ingredients or ingredientcombinations.

As used herein, “carrier” means an optional material, including but notlimited to a solid or fluid, that can be combined with a benefit agent(e.g., conditioning polymers) to facilitate delivery and/or use of thebenefit agent.

As used herein, the term “solid” includes granular, powder, bar andtablet product forms.

As used herein, the term “fluid” includes liquid, gel, paste and gasproduct forms including unitized-dose forms that generally include afluid composition enclosed in a pouch or other delivery vehicle.

As used herein, the term “particle” includes solid and semi-solidparticles, as well as emulsion droplets.

Unless otherwise indicated, all percentages and ratios herein arecalculated based on weight.

All percentages and ratios are calculated based on weight of the totalcomposition unless otherwise indicated.

Unless specified otherwise, all molecular weights are given in Daltons.

Unless otherwise indicated, all molecular weights are weight averagemolecular weights as determined by size exclusion chromatography using aMALS detector (SEC-MALS), as is commonly known by those skilled in theart. A MALS detector (Multi-Angle Light Scattering Detector, such asthose manufactured by Malvern Instruments Ltd., Malvern, UK) determinesabsolute molecular weight, rather than relative molecular weight (i.e.,determined relative to a standard).

Unless otherwise noted, all component (i.e., ingredient) or compositionlevels are in reference to the active portion of that component orcomposition, and are exclusive of impurities, for example, residualsolvents or by-products, which may be present in commercially availablesources of such components or compositions.

The term “charge density”, as used herein, refers to the ratio of thenumber of positive charges on a monomeric unit of which a polymer iscomprised, to the molecular weight of said monomeric unit. The chargedensity multiplied by the polymer molecular weight determines the numberof positively charged sites on a given polymer chain. The charge densitycalculation can also be expressed as:

${{charge}\mspace{14mu}{density}} = {\frac{\left( {{moles}\mspace{14mu}{of}\mspace{14mu} N} \right)\left( {{charge}\mspace{14mu}{per}\mspace{14mu} N} \right)}{\left( {{moles}\mspace{14mu}{of}\mspace{14mu}{polymer}} \right)\left( {{molecular}\mspace{14mu}{weight}\mspace{14mu}{of}\mspace{14mu}{the}\mspace{14mu}{polymer}} \right)} \times 100}$

As used herein, the term “hydrocarbon polymer radical” means a polymericradical comprising only carbon and hydrogen.

As used herein, “ethylene moiety” means a divalent CH₂CH₂ moiety.

As used herein, the term “siloxyl residue” means a polydialkylsiloxanemoiety.

As used herein, the nomenclature SiO_(n/2) represents the ratio ofoxygen and silicon atoms. For example, SiO_(1/2) means that, on average,one oxygen atom is shared between two silicon atoms. Likewise SiO_(2/2)means that, on average, two oxygen atoms are shared between two siliconatoms and SiO_(3/2) means that, on average, three oxygen atoms areshared between two silicon atoms.

As used herein, the terms “substantially no”, “substantially free of”,and/or “substantially free from” mean that the indicated material is atthe very minimum not deliberately added to the composition to form partof it, or, preferably, is not present at analytically detectable levels.It is meant to include compositions whereby the indicated material ispresent only as an impurity in one of the other materials deliberatelyincluded.

It should be understood that every maximum numerical limitation giventhroughout this specification includes every lower numerical limitation,as if such lower numerical limitations were expressly written herein.Every minimum numerical limitation given throughout this specificationwill include every higher numerical limitation, as if such highernumerical limitations were expressly written herein. Every numericalrange given throughout this specification will include every narrowernumerical range that falls within such broader numerical range, as ifsuch narrower numerical ranges were all expressly written herein.

II. Blocky Cationic Organopolysiloxane Polymers

The present invention provides a blocky cationic organopolysiloxanehaving the formula:M_(w)D_(x)T_(y)Q_(z)wherein:

-   -   M is selected from the group consisting of [SiR₁R₂R₃O_(1/2)],        [SiR₁R₂G₁O_(1/2)], [SiR₁G₁G₂O_(1/2)], [SiG₁G₂G₃O_(1/2)], and        combinations thereof;    -   D is selected from the group consisting of [SiR₁R₂O_(2/2)],        [SiR₁G₁O_(2/2)], [SiG₁G₂O_(2/2)], and combinations thereof;    -   T is selected from the group consisting of [SiR₁O_(3/2)],        [SiG₁O_(3/2)], and combinations thereof;    -   Q=[SiO_(4/2)];    -   w is an integer from 1 to about (2+y+2z);    -   x is an integer from about 5 to about 15,000;    -   y is an integer from 0 to about 98;    -   z is an integer from 0 to about 98;    -   R₁, R₂ and R₃ are each independently selected from the group        consisting of H, OH, C₁-C₃₂ alkyl, C₁-C₃₂ substituted alkyl,        C₅-C₃₂ or C₆-C₃₂ aryl, C₅-C₃₂ or C₆-C₃₂ substituted aryl, C₆-C₃₂        alkylaryl, C₆-C₃₂ substituted alkylaryl, C₁-C₃₂ alkoxy, C₁-C₃₂        substituted alkoxy, C₁-C₃₂ alkylamino, and C₁-C₃₂ substituted        alkylamino;    -   and wherein at least one of M, D, and T incorporates at least        one moiety G₁, G₂ or G₃ and G₁, G₂, and G₃ are same or different        moieties each of which has the formula:

-   -   wherein:        -   X comprises a divalent radical selected from the group            consisting of C₁-C₃₂ alkylene, C₁-C₃₂ substituted alkylene,            optionally interrupted with a hetero atom selected from the            group consisting of P, N and O, C₅-C₃₂ or C₆-C₃₂ arylene,            C₅-C₃₂ or C₆-C₃₂ substituted arylene, C₆-C₃₂ arylalkylene,            C₆-C₃₂ substituted arylalkylene, C₁-C₃₂ alkyleneamino,            C₁-C₃₂ substituted alkyleneamino, ring-opened epoxide and            ring-opened glycidyl;        -   N is a nitrogen atom;        -   Each R₄ and each is independently selected from the group            consisting of H,

-   -   -   C₁-C₃₂ alkyl, C₁-C₃₂ substituted alkyl, C₅-C₃₂ or C₆-C₃₂            aryl, C₅-C₃₂ or C₆-C₃₂ substituted aryl, C₆-C₃₂ alkylaryl,            and C₆-C₃₂ substituted alkylaryl;        -   Wherein;        -   Each E comprises the same or different divalent radicals            selected from the group consisting of C₁-C₃₂ alkylene,            C₁-C₃₂ substituted alkylene, alkylene, optionally            interrupted with a hetero atom selected from the group            consisting of P, N and O, C₅-C₃₂ or C₆-C₃₂ arylene, C₅-C₃₂            or C₆-C₃₂ substituted arylene, C₆-C₃₂ arylalkylene, C₆-C₃₂            substituted arylalkylene, C₁-C₃₂ alkoxy, C₁-C₃₂ substituted            alkoxy, C₁-C₃₂ alkyleneamino, C₁-C₃₂ substituted            alkyleneamino, ring-opened epoxide and ring-opened glycidyl;        -   Each R₅ is independently selected from the group consisting            of H, C₁-C₃₂ alkyl, C₁-C₃₂ substituted alkyl, C₅-C₃₂ or            C₆-C₃₂ aryl, C₅-C₃₂ or C₆-C₃₂ substituted aryl, C₆-C₃₂            alkylaryl, and C₆-C₃₂ substituted alkylaryl; or R₅ comprises            one or more M_(w)D_(x)T_(y)Q_(z) moieties;        -   And wherein at least one R5 comprises at least one            M_(w)D_(x)T_(y)Q_(z) moiety

    -   And wherein:

    -   Each m is an integer independently selected from 2 to 100,

    -   Each n is an integer independently selected from 1 or 2,

    -   And when an organopolysiloxane portion of a moiety G₁, G₂, G₃ is        positively charged, A^(−t) is a suitable charge balancing anion        or anions such that the total charge of all occurrences of the        charge-balancing anion or anions, A^(−t) and kA^(−t), is equal        to and opposite from the net charge on the organopolysiloxane        portions of the moiety G₁, G₂ or G₃.        -   It would be appreciated by one of ordinary skill in the art            that:        -   A is an anionic counter ion to the positively charge            organopolysiloxane,        -   t is the charge on any individual counter ion, and        -   k is the coefficient of any such counterion            so that the net charge of the positively charge            organopolysiloxane and the sum total of the counter ions is            neutral.

In one embodiment, the blocky cationic organopolysiloxane has theformula:

Wherein:D is [SiR₁R₂O_(2/2)],x is an integer independently selected from about 40 to about 1000,R₁, R₂ and are independently selected from the group consisting of H,OH, C₁-C₃₂ alkyl, C₁-C₃₂ substituted alkyl, C₅-C₃₂ or C₆-C₃₂ aryl,C₅-C₃₂ or C₆-C₃₂ substituted aryl, C₆-C₃₂ alkylaryl, C₆-C₃₂ substitutedalkylaryl, C₁-C₃₂ alkoxy, C₁-C₃₂ substituted alkoxy,wherein;

-   -   Each X comprises a divalent radical selected from the group        consisting of C₁-C₃₂ alkylene, C₁-C₃₂ substituted alkylene,        optionally interrupted with a hetero atom selected from the        group consisting of P, N and O, C₅-C₃₂ or C₆-C₃₂ arylene, C₅-C₃₂        or C₆-C₃₂ substituted arylene, C₆-C₃₂ arylalkylene, C₆-C₃₂        substituted arylalkylene, C₁-C₃₂ alkyleneamino, C₁-C₃₂        substituted alkyleneamino, ring-opened epoxide and ring-opened        glycidyl;    -   Each R₄ is independently selected from the group consisting of        H,

-   -   C₁-C₃₂ alkyl, C₁-C₃₂ substituted alkyl, C₅-C₃₂ or C₆-C₃₂ aryl,        C₅-C₃₂ or C₆-C₃₂ substituted aryl, C₆-C₃₂ alkylaryl, and C₆-C₃₂        substituted alkylaryl;    -   N is a nitrogen atom;    -   Each R₅ is, independently, selected from the group consisting of        H, C₁-C₃₂ alkyl, C₁-C₃₂ substituted alkyl, C₅-C₃₂ or C₆-C₃₂        aryl, C₅-C₃₂ or C₆-C₃₂ substituted aryl, C₆-C₃₂ alkylaryl, and        C₆-C₃₂ substituted alkylaryl optionally interrupted with a        hetero atom selected from the group consisting of P, N and O,        C₁-C₃₂ alkoxy, C₁-C₃₂ substituted alkoxy, C₁-C₃₂ alkylamino, or        C₁-C₃₂ substituted alkylamino;    -   Each E comprises same or different divalent radicals selected        from the group consisting of C₁-C₃₂ alkylene, C₁-C₃₂ substituted        alkylene, alkylene, optionally interrupted with a hetero atom        selected from the group consisting of P, N and O, C₅-C₃₂ or        C₆-C₃₂ arylene, C₅-C₃₂ or C₆-C₃₂ substituted arylene, C₆-C₃₂        arylalkylene, C₆-C₃₂ substituted arylalkylene, C₁-C₃₂ alkoxy,        C₁-C₃₂ substituted alkoxy, C₁-C₃₂ alkyleneamino, C₁-C₃₂        substituted alkyleneamino, ring-opened epoxide and ring-opened        glycidyl;    -   Each m is an integer independently selected from 2 to 100,    -   Each n is an integer independently selected from 1 or 2,    -   f is an integer from 2 to about 50,    -   And A^(−t) is a suitable charge balancing anion or anions such        that the total charge of all occurrences of the charge-balancing        anion or anions, A^(−t) and kA^(−t), is equal to and opposite        from the net charge on the blocky cationic organopolysiloxane.

In one embodiment, A^(−t) is selected from the group consisting of Cl—,Br—, I—, methylsulfate, toluene sulfonate, carboxylate, phosphate,hydroxide, acetate, formate, carbonate, nitrate, and combinationsthereof.

In one embodiment that blocky cationic organopolysiloxane has thestructure:

Wherein:D is [SiR₁R₂O_(2/2)],x is an integer independently selected from about 40 to about 1000,R₁, R₂ and are independently selected from the group consisting of H,OH, C₁-C₃₂ alkyl, C₁-C₃₂ substituted alkyl, C₅-C₃₂ or C₆-C₃₂ aryl,C₅-C₃₂ or C₆-C₃₂ substituted aryl, C₆-C₃₂ alkylaryl, C₆-C₃₂ substitutedalkylaryl, C₁-C₃₂ alkoxy, C₁-C₃₂ substituted alkoxy,wherein;

-   -   Each X comprises a divalent radical selected from the group        consisting of C₁-C₃₂ alkylene, C₁-C₃₂ substituted alkylene,        optionally interrupted with a hetero atom selected from the        group consisting of P, N and O, C₅-C₃₂ or C₆-C₃₂ arylene, C₅-C₃₂        or C₆-C₃₂ substituted arylene, C₆-C₃₂ arylalkylene, C₆-C₃₂        substituted arylalkylene, C₁-C₃₂ alkyleneamino, C₁-C₃₂        substituted alkyleneamino;    -   Each R₄ is independently selected from the group consisting of        H,

-   -   C₁-C₃₂ alkyl, C₁-C₃₂ substituted alkyl, C₅-C₃₂ or C₆-C₃₂ aryl,        C₅-C₃₂ or C₆-C₃₂ substituted aryl, C₆-C₃₂ alkylaryl, and C₆-C₃₂        substituted alkylaryl;    -   N is a nitrogen atom;    -   Each R₅ is, independently, selected from the group consisting of        H, C₁-C₃₂ alkyl, C₁-C₃₂ substituted alkyl, C₅-C₃₂ or C₆-C₃₂        aryl, C₅-C₃₂ or C₆-C₃₂ substituted aryl, C₆-C₃₂ alkylaryl, and        C₆-C₃₂ substituted alkylaryl, optionally interrupted with a        hetero atom selected from the group consisting of P, N and O,        C₁-C₃₂ alkoxy, C₁-C₃₂ substituted alkoxy, C₁-C₃₂ alkylamino,        C₁-C₃₂ substituted alkylamino;    -   Each E comprises same or different divalent radicals selected        from the group consisting of C₁-C₃₂ alkylene, C₁-C₃₂ substituted        alkylene, alkylene, optionally interrupted with a hetero atom        selected from the group consisting of P, N and O, C₅-C₃₂ or        C₆-C₃₂ arylene, C₅-C₃₂ or C₆-C₃₂ substituted arylene, C₆-C₃₂        arylalkylene, C₆-C₃₂ substituted arylalkylene, C₁-C₃₂ alkoxy,        C₁-C₃₂ substituted alkoxy, C₁-C₃₂ alkyleneamino, C₁-C₃₂        substituted alkyleneamino, ring-opened epoxide and ring-opened        glycidyl;    -   Each m is an integer independently selected from 2 to 100,    -   Each n is an integer independently selected from 1 or 2,    -   f is an integer from 2 to about 50,    -   And A^(−t) is a suitable charge balancing anion or anions such        that the total charge of all occurrences of the charge-balancing        anion or anions, A^(−t) and kA^(−t), is equal to and opposite        from the net charge on the blocky cationic organopolysiloxane.

III. Methods of Making the Blocky Cationic Organopolysiloxane

Embodiments of the present invention can be made as follows. An amountof functional silicone is added to a clean vessel under inertatmosphere. The functional silicone may be an amino functional siliconeor a silicone with an organic group capable of reacting with an aminofunction, examples of organic groups capable of reacting with an aminofunction include halogen functional silicone or an epoxy functionalsilicone. Optionally, a solvent such as isopropanol or tetrahydrofuranis added. The reaction is optionally mixed and quantities of diamine anddifunctional organic compounds capable of reacting with the aminofunctions of the amine compounds are added, either simultaneously orsequentially. For example, the difunctional organic compound capable ofreacting with the amino function may be added first and the diamineadded second, to obtain the desired organopolysiloxane. Alternately,these reagents may be added in reverse order.

The reaction is run at a temperature appropriate for the reagents. Forexample, when the difunctional organic compound capable of reacting withthe amino functions is a dichloride, the reaction may be run atrelatively higher temperatures (typically above 60° C. and often above80° C.). Alternately, when the difunctional organic compound capable ofreacting with the amino functions is a dibromide, the reaction may berun at relatively lower temperatures, including at room temperature(e.g., 21° C.). Alternately, when the difunctional organic compoundcapable of reacting with the amino functions is an activated dichloride,the reaction may be run at relatively lower temperatures, including atroom temperature (e.g., 21° C.). One of ordinary skill in the art wouldunderstand the reaction conditions suitable for the specificdifunctional organic compound capable of reacting with the aminofunctions.

The above making process is also generally described by Lange (U.S. Pat.No. 7,563,856). One skilled in the art would understand how the generalprocess disclosed in Lange can be reapplied to the present developmentin order to produce the organopolysiloxanes of the present invention.

In one embodiment, the reaction is run without the addition of solvent,resulting in a substantially solvent-free process for making theorganopolysiloxane of the present invention.

In another embodiment, the reaction is run and subsequently excess amineis added. Without being bound by theory, it is believed that the excessamine will consume the reactive groups of any residual difunctionalorganic compounds capable of reacting with the amino functions.

In another embodiment, the reaction mixture is further reacted with anamine containing molecule. Non-limiting examples of such amines includeammonia, methylamine, dimethylamine, trimethylamine, triethylamine orethanolamine or diethanolamine. Without being bound by theory it isbelieved that this further reaction caps un-reacted alkyl-halidefunctionality.

In another embodiment, the reaction mixture is further reacted with amono-functional organic species capable of reacting with the aminefunctionality of the organopolysiloxane. Non-limiting examples of suchmono-functional organic species include: methyl bromide, methyl iodide,and ethylbromide. Without being bound by theory it is believed that thisfurther reaction helps to quaternize any residual neutral amine groupsof the organopolysiloxane, including the terminal amine functionality.

IV. Uses of the Organopolysiloxane Compositions

The organopolysiloxanes according to the present invention can beformulated into a variety of consumer product compositions that can beapplied to substrates in order to impart consumer-desired benefits, suchas conditioning. Such substrates can include fabric, non-wovenmaterials, paper products, hard surface materials, and biologicalmaterials (e.g., keratinous materials such as hair or skin).

The consumer product compositions comprising the organopolysiloxanepolymers of the present invention may be prepared by any suitableprocess, such as processes known by those skilled in the art. Forexample, the organopolysiloxane polymers can be incorporated directlyinto the composition's other ingredients without pre-emulsificationand/or pre-mixing to form the finished products. Alternatively, theorganopolysiloxane may be mixed with surfactants, solvents, suitableadjuncts, and/or any other suitable ingredients to prepare emulsionsprior to compounding the finished products.

The consumer product composition can comprise one or more surfactants.The surfactants may comprise cationic, anionic, non-ionic, zwitterionic,and/or amphoteric surfactants. In one embodiment, at least onesurfactant is anionic. Various forms of the consumer product compositioncan be aqueous or non-aqueous; in one embodiment, an aqueous compositionhas a pH greater than 3, or greater than 5.

The composition may also comprise at least one benefit agent. Benefitagents can be hydrophobic or hydrophilic. Useful hydrophobic benefitagents include silicones, vinyl polymers, polyethers, materialscomprising a hydrocarbon wax, hydrocarbon liquids, fluid sugarpolyesters, fluid sugar polyethers, and mixtures thereof. In oneembodiment, the silicones that are useful as benefit agents areorganosilicones. In another embodiment, the silicone benefit agent isselected from the group consisting of a polydimethylsiloxane, anaminosilicone, a cationic silicone, a silicone polyether, a cyclicsilicone, a silicone resin, a fluorinated silicone, and mixturesthereof. In one embodiment, the benefit agent is a liquid at roomtemperature. In another embodiment, the benefit agent is a solid orsemi-solid at room temperature. In one embodiment, the benefit agent isa perfume or a silicone. Further, the benefit agent may be encapsulated.In one embodiment, the benefit agent is an encapsulated perfume.

The organopolysiloxane may be pre-emulsified prior to compounding into aconsumer product composition. In one embodiment, a benefit agent isincluded with the organopolysiloxane in the pre-emulsion. In oneembodiment, the benefit agent and the organopolysiloxane mixture canform a particle in the pre-emulsion.

Materials which may be helpful in creating such emulsions include:Tergitol 15-S-5, Terigtol 15-S-12, and TMN-10. The suspensions can bemade by mixing the components together using a variety of mixingdevices. Examples of suitable overhead mixers include: IKA Labortechnik,and Janke & Kunkel IKA WERK, equipped with impeller blade DivtechEquipment R1342. In some cases, high shear processing is required toobtain a narrow particle size distribution. Example of a suitable highshear processing device is M-110P Microfluidizer from Microfluidics.

EXAMPLES

The following examples further describe and demonstrate exemplaryembodiments within the scope of the present invention. The examples aregiven solely for the purpose of illustration and are not to be construedas limitations of the present invention since many variations thereofare possible without departing from the spirit and scope of theinvention. Ingredients are identified by chemical name, or otherwisedefined below.

To a clean vessel is added the quantity of silicones (available fromGelest Co., Morrisville, Pa.) shown in Table 1 and an amount ofisopropanol (available from Sigma-Aldrich, Milwaukee, Wis.) equal to theamount of silicone is added. This is mixed by stirring the sample at 30rpm for one hour and then the quantity of activated dichloride(available from Sigma-Aldrich, Milwaukee, Wis.) is added along with theamount of dihalide indicated for the 1^(st) addition and this is mixedby stirring at 30 rpm for 12 hours at 50° C. After twelve hours, thequantity of diamine (available from Sigma-Aldrich, Milwaukee, Wis.)shown in the table indicated for the 2^(nd) addition is added. This isfollowed by heating the sample at 50° C. for 16 hours.

TABLE 1 Weight (g) Example Amino Silicone Weight (g) Molecular WeightWeight (g) Weight (g) Diamine Diamine # starting material¹ Silicone(Daltons) Silicone x Dihalide (1st adition) Dihalide (2nd adition) 1DMS-A15 50 g 3000 40 16.27 g 8.60 g Dibromo 2.87 g Hexane 2 DMS-A15 25 g3000 40 40.67 g 27.23 g  Dibromo 1.44 g Hexane 3 DMS-A32 250 g  30000400  8.13 g 2.87 g Dibromo 2.87 g Hexane 4 DMS-A32 100 g  30000 40032.53 g 22.36 g  Dibromo 0.57 g Hexane 5 DMS-A32 500 g  30000 400 21.87g 8.60 g Dibromo 2.87 g Dodecane 6 DMS-A32 250 g  30000 400  7.20 g 4.30g Dibromo 1.43 g Butane 7 DMS-A15 50 g 3000 40 41.67 g 54.47 g 1,4-dichloro-2- 2.96 g butene 8 DMS-A32 50 g 30000 400  1.67 g 1.15 g1,4-dichloro-2- 1.15 g butene 9 DMS-A32 50 g 30000 400  4.17 g 5.45 g1,4-dichloro-2- 0.28 g butene 10 DMS-A32 100 g  30000 400  2.92 g 1.55 gp-dichloroxylene 0.38 g ¹= catalogue numbers of aminosilicone startingmaterial, available from Gelest Company, Morrisville, PA)End-Use Formulations:

Exemplary organopolysiloxanes of the present invention are formulatedinto different product chassis to make various consumer productformulations. In some embodiments, the organopolysiloxane is added tothe ingredient mixture in the form of an emulsion.

Emulsion Preparation:

The following emulsions are prepared for use in the consumer productformulation examples set forth herein.

The organopolysiloxanes from Examples 1-10 above are used to make theemulsions used in making the consumer product formulation examplesbelow.

The organopolysiloxanes from Examples 1-10 are first emulsified using ahomogenizer at 3,500 rpm, and then microfluidized at 20,000 psi toobtain sub-micron size emulsions (mean particle size 250 nm, as measuredusing Horriba instrumentation as known in the art).

TABLE 2 Material % Organopolysiloxane of Examples 1-10 20.00 Tergitol15-S-5¹ 3.00 Acetic Acid 0.60 Dilution Water q.s. to 100% ¹Availablefrom Sigma AldrichHair Care Compositions Comprising the Organopolysiloxanes:

Examples below list non-limiting examples of hair care shampoo andconditioner compositions comprising emulsions of the organopolysiloxaneconditioning polymers of the present invention.

Shampoos are prepared as follows:

Material % active in shampoo Deionized Water q.s. to 100% SLE1S ¹ 10.50%CMEA ²  0.85% Na₄EDTA  0.14% NaBenzoate  0.25% Citric acid  0.22% SLS ³ 1.50% CAPB ⁴  1.00% Kathon  0.03% Emulsion according to Table 2  5.00%C500 Guar ⁵  0.25% ¹ Sodium Laureth Sulfate, 28% active, supplier: P&G ²Cocoamide MEA available as Monamid CMA, 85% active, available fromGoldschmidt Chemical ³ Sodium Lauryl Sulfate, 29% active from P&G ⁴Cocoamidopropyl Betaine available as Tego ® betaine F-B, 30% active,available from Goldschmidt Chemicals ⁵ Jaguar ® C500, MW - 500,000, CD =0.7, available from RhodiaIngredients are combined and mixed by conventional means as known by oneof ordinary skill in the art.Hair Conditioners are prepared as follows:

Material % active in conditioner Cetyl Alcohol 1.21% Stearyl Alcohol3.00% Behentrimonium methosulfate/IPA ¹ 2.47% Benzyl Alcohol 0.43%Deionized Water q.s. to 100% Perfume 0.59% EDTA 0.15% Emulsionsaccording to Table 2 5.00% ¹ Behentrimonium methosulfate/Isopropylalcohol, available as Genamin BTMS from Clariant

Ingredients are combined and mixed by conventional means as known by oneof ordinary skill in the art.

Top Sheets and Paper:

It can be appreciated by one of ordinary skill in the art that any of anumber of means of applying the organopolysiloxane to the nonwoven canbe utilized. The organopolysiloxane may be emulsified prior toapplication to the nonwoven, including emulsification into water orother primarily aqueous carrier. The organopolysiloxane may be dissolvedin a suitable carrier prior to application to the nonwoven. The carriermay be volatile to facilitate removal of the carrier after treatment ofthe nonwoven. In one non-limiting example of the present invention, anyof the organopolysiloxanes of Examples 1-10 is emulsified as describedin Table 2 and air sprayed onto a 24 gsm (grams per square meter)non-woven top sheet to obtain a final coating of 5 gsm. Top sheets areair dried overnight and allowed to equilibrate in a controlled humidityroom.

Fabric Care Compositions:

Examples below list non-limiting examples of Fabric Care compositioncomprising mulsions of the organopolysiloxane conditioning polymers ofthe present invention.

Heavy Duty Liquid (HDL) laundry detergent formula are prepared asfollows:

Material % in HDL HDL AE1.8S Paste¹ 26.83 DTPA 50% ACTIVE² 0.63 HDLBrightener 15 Premix³ 3.03 Monoethanolamine (MEA) 2.26 C₁₂/C₁₄ AMINEOXIDE⁴ 1.69 Alkoxylated polyamine HOD Base⁵ 1.20 CAUSTIC SODA (NaOH)0.53 Anionic Detergent Blend MVP-2 Paste⁶ 4.25 Borax Premix for HDL⁷6.06 C11.8 HLAS⁸ 4.19 CITRIC ACID SOLUTION⁹ 5.34 C12-18 FATTY ACID¹⁰1.42 CALCIUM FORMATE 0.84 Water q.s. to 100% Subtilisins (NFNA-HA Base)¹¹ - (54.5 mg/g) 1.27 MANNANASE ( 25.6 mg/g) 0.06 NATALASE (29.26 mg/g)0.31 Polyethyleneimine Ethoxylate PE-20 (ODD-Base)¹² 1.89 Emulsionsaccording to Table 2 20.00 ¹Available from Shell Chemicals, Houston, TX²Diethylenetriaminepentaacetic acid, sodium salt ³Available from TheProcter & Gamble Company, Cincinnati, OH ⁴Available from The Procter &Gamble Company, Cincinnati, OH ⁵Available from BASF, AG, Ludwigshafen⁶Available from The Procter & Gamble Company, Cincinnati, OH ⁷Availablefrom Univar, Cincinnati, OH ⁸Available from Huntsman Chemicals, SaltLake City, UT ⁹Available from Ciba Specialty Chemicals, High Point, NC¹⁰Available from Enencor International, South San Francisco, CA.¹¹Available from Genencor, Rochester, NY ¹²Available from BASF, AG,Ludwigshafen

Ingredients are combined and mixed by conventional means as known by oneof ordinary skill in the art.

Fabric Softener compositions are prepared as follows:

EXAMPLE COMPOSITION 78 Fabric Softener Active¹ 11.0 Fabric SoftenerActive² — Cationic Starch³ — Polyethylene imine⁴ — Quaternizedpolyacrylamide⁵ 0.2 Calcium chloride 0.15 Ammonium chloride 0.1 SudsSuppressor⁶ — Emulsions according to Table 2 15.0 Perfume 2.0 Perfumemicrocapsule⁷ 0.75 Water, suds suppressor, stabilizers, pH controlagents, q.s. to 100% buffers, dyes & other optional ingredients pH = 3.0¹N,N di(tallowoyloxyethyl) - N,N dimethylammonium chloride availablefrom Evonik Corporation, Hopewell, VA. ²Reaction product of fatty acidwith Methyldiethanolamine, quaternized with Methylchloride, resulting ina 2.5:1 molar mixture of N,N-di(tallowoyloxyethyl) N,N-dimethylammoniumchloride and N-(tallowoyloxyethyl) N-hydroxyethyl N,N-dimethylammoniumchloride available from Evonik Corporation, Hopewell, VA. ³Cationicstarch based on common maize starch or potato starch, containing 25% to95% amylose and a degree of substitution of from 0.02 to 0.09, andhaving a viscosity measured as Water Fluidity having a value from 50 to84. Available from National Starch, Bridgewater, NJ ⁴Available fromNippon Shokubai Company, Tokyo, Japan under the trade name Epomin 1050.⁵Cationic polyacrylamide polymer such as a copolymer ofacrylamide/[2-(acryloylamino)ethyl]tri-methylammonium chloride(quaternized dimethyl aminoethyl acrylate) available from BASF, AG,Ludwigshafen under the trade name Sedipur 544. ⁶SILFOAM ® SE90 availablefrom Wacker AG of Munich, Germany ⁷Available from Appleton Paper ofAppleton, WI

Ingredients are combined and mixed by conventional means as known by oneof ordinary skill in the art.

The dimensions and values disclosed herein are not to be understood asbeing strictly limited to the exact numerical values recited. Instead,unless otherwise specified, each such dimension is intended to mean boththe recited value and a functionally equivalent range surrounding thatvalue. For example, a dimension disclosed as “40 mm” is intended to mean“about 40 mm.”

Every document cited herein, including any cross referenced or relatedpatent or application and any patent application or patent to which thisapplication claims priority or benefit thereof, is hereby incorporatedherein by reference in its entirety unless expressly excluded orotherwise limited. The citation of any document is not an admission thatit is prior art with respect to any invention disclosed or claimedherein or that it alone, or in any combination with any other referenceor references, teaches, suggests or discloses any such invention.Further, to the extent that any meaning or definition of a term in thisdocument conflicts with any meaning or definition of the same term in adocument incorporated by reference, the meaning or definition assignedto that term in this document shall govern.

While particular embodiments of the present invention have beenillustrated and described, it would be obvious to those skilled in theart that various other changes and modifications can be made withoutdeparting from the spirit and scope of the invention. It is thereforeintended to cover in the appended claims all such changes andmodifications that are within the scope of this invention.

What is claimed is:
 1. A blocky cationic organopolysiloxane having thestructure:

wherein: D is [SiR₁R₂O_(2/2)], x is an integer independently selectedfrom about 40 to about 1000, R₁ and R₂ are independently selected fromthe group consisting of H, OH, C₁-C₃₂ alkyl, C₁-C₃₂ substituted alkyl,C₅-C₃₂ aryl, C₅-C₃₂ substituted aryl, C₆-C₃₂ alkylaryl, C₆₋₃₂substituted alkylaryl, C₁-C₃₂ alkoxy, C₁-C₃₂ substituted alkoxy,wherein: each X comprises a divalent radical selected from the groupconsisting of C₁-C₃₂ alkylene, C₅-C₃₂ arylene, C₅-C₃₂ substitutedarylene, C₆-C₃₂ arylalkylene, C₆-C₃₂ substituted arylalkylene, C₁-C₃₂alkyleneamino, and C₁-C₃₂ substituted alkyleneamino; each R₄ isindependently selected from the group consisting of H,

 C₁-C₃₂ alkyl, C₁-C₃₂ substituted alkyl, C₅-C₃₂ aryl, C₅-C₃₂ substitutedaryl, C₆-C₃₂ alkylaryl, and C₆-C₃₂ substituted alkylaryl; N is anitrogen atom; each R₅ is, independently, selected from the groupconsisting of H, C₁-C₃₂ alkyl, C₁-C₃₂ substituted alkyl, C₅-C₃₂ aryl,C₅-C₃₂ substituted aryl, C₆-C₃₂ alkylaryl, C₆-C₃₂ substituted alkylaryloptionally interrupted with a hetero atom selected from the groupconsisting of P, N, and O, C₁-C₃₂ alkoxy, C₁-C₃₂ substituted alkoxy,C₁-C₃₂ alkylamino, and C₁-C₃₂ substituted alkylamino; each E comprisessame or different divalent radicals selected from the group consistingof C₁-C₃₂ alkylene, C₅-C₃₂ arylene, C₅-C₃₂ substituted arylene, C₆-C₃₂arylalkylene, C₆-C₃₂ substituted arylalkylene, C₁-C₃₂ alkoxy, C₁-C₃₂substituted alkoxy, C₁-C₃₂ alkyleneamino, and C₁-C₃₂ substitutedalkyleneamino; each m is an integer independently selected from 2 to100, each n is an integer independently selected from 1 or 2, f is aninteger from 2 to about 50, and A^(−t) is a suitable charge balancinganion or anions such that the total charge of all occurrences of thecharge-balancing anion or anions, A^(−t) and kA^(−t), is equal to andopposite from the net charge on the blocky cationic organopolysiloxane.2. A blocky cationic organopolysiloxane according to claim 1, whereinA^(−t) is selected from the group consisting of Cl—, Br—, I—,methylsulfate, toluene sulfonate, carboxylate, phosphate, hydroxide,acetate, formate, carbonate, nitrate, and combinations thereof.
 3. Acleansing or surface-treatment consumer product composition comprising:(a) surfactant selected from the group consisting of anionic surfactant,nonionic surfactant, zwitterionic surfactant, amphoteric surfactant,cationic surfactant, and mixtures thereof; and (b) a blocky cationicorganopolysiloxane according to claim
 1. 4. The composition of claim 3,which is selected from the group consisting of hair care compositions,fabric care compositions, skin care compositions, shampoos, hairconditioners, bodywashes, hair mousses, gels, pomades, sprays, laundrydetergents, fabric softeners, antimicrobial washes, hard surfacecleaners, and carpet cleaners.
 5. The composition of claim 3, whereinthe composition further comprises one or more adjuncts selected from thegroup consisting of bleaches, bleach activators, surfactants, builders,chelating agents, dye transfer inhibiting agents, dispersants, enzymes,enzyme stabilizers, catalytic metal complexes, polymers, polymericdispersing agents, clay and soil removal/anti-redeposition agents,brighteners, fluorescent whitening agents, suds suppressors, dyes,perfumes, perfume delivery systems, structure elasticizing agents,fabric softeners, carriers, hydrotropes, solvents, processing aids, dyefixatives conditioning agents, perfumes, perfume microcapsules,emoliants, fatty alcohols, delivery enhancing agents, pigments, andmixtures thereof.
 6. The composition of claim 3, which is a fabric carecomposition comprising a surfactant is selected from linear or branchedalkyl benzene sulfonate, alkyl sulfate, alkyl ethoxy sulfate, alkylethoxylate, alkyl glyceryl sulfonate, quaternary ammonium surfactant,ester quaternary ammonium compound, and mixtures thereof.
 7. Thecomposition of claim 3, further comprising a benefit agent selected fromthe group consisting silicones, silicone resins, silicone waxes, vinylpolymers, hydrocarbon waxes, hydrocarbon liquids, sugar polyesters,sugar polyethers, perfume raw materials, hydrocarbon waxes, polyolefinwaxes, polyethylene waxes, polypropylene waxes, modified polyethyleneand polypropylene waxes and copolymers thereof, polyisobutene,substituted polyisobutene, isobutene copolymers, essential oils, lipids,skin coolants, vitamins, sunscreens, antioxidants, glycerine, catalysts,bleach particles, silicon dioxide particles, malodor reducing agents,odor-controlling materials, chelating agents, antistatic agents,softening agents, insect and moth repelling agents, colorants,antioxidants, chelants, bodying agents, drape and form control agents,smoothness agents, wrinkle control agents, sanitization agents,disinfecting agents, germ control agents, mold control agents, mildewcontrol agents, antiviral agents, drying agents, stain resistanceagents, soil release agents, fabric refreshing agents and freshnessextending agents, chlorine bleach odor control agents, dye fixatives,dye transfer inhibitors, color maintenance agents, optical brighteners,color restoration/rejuvenation agents, anti-fading agents, whitenessenhancers, anti-abrasion agents, wear resistance agents, fabricintegrity agents, anti-wear agents, anti-pilling agents, defoamers,anti-foaming agents, UV protection agents, sun fade inhibitors,anti-allergenic agents, enzymes, water proofing agents, fabric comfortagents, shrinkage resistance agents, stretch resistance agents, stretchrecovery agents, skin care agents, glycerin, natural actives,antibacterial actives, antiperspirant actives, delivery enhancingagents, cationic polymers, dyes emoliants, fatty alcohols, gel networks,and mixtures thereof.
 8. The composition of claim 7, wherein the benefitagent is selected from the group consisting of silicones, siliconeresins, silicone waxes, and mixtures thereof.
 9. The composition ofclaim 3, comprising an adjunct selected from the group consisting of: a)an anionic surfactant selected from the group consisting of a C₁₁-C₁₈alkyl benzene sulfonate surfactant; a C₁₀-C₂₀ alkyl sulfate surfactant;a C₁₀-C₁₈ alkyl alkoxy sulfate surfactant, said C₁₀-C₁₈ alkyl alkoxysulfate surfactant having an average degree of alkoxylation of from 1 to30 and the alkoxy comprises a C₁-C₄ chain, alkyls, alkyl ether sulfates,succinates, olefin sulfonates, beta-alkyloxy alkane sulfonates, andmixtures thereof, b) a cationic surfactant selected from the groupconsisting of mono-long alkyl quaternized ammonium salt cationicsurfactants, mono-alkyl amines, di-alkyl chain cationic surfactants, andmixtures thereof, c) a conditioning active selected from the groupconsisting of silicones (e.g., silicone oils, cationic silicones,silicone gums, high refractive silicones, and silicone resins), organicconditioning oils (e.g., hydrocarbon oils, polyolefins, and fattyesters), other conditioning agents which form liquid, dispersedparticles in an aqueous surfactant matrix, and combinations thereof, d)a perfume delivery system comprising a perfume microcapsule or amoisture-activated perfume microcapsule comprising a perfume carrier andan encapsulated perfume composition, wherein said perfume carrier isselected from the group consisting of cyclodextrins, starchmicrocapsules, porous carrier microcapsules, and mixtures thereof; andwherein said encapsulated perfume composition comprises low volatileperfume ingredients, high volatile perfume ingredients, a pro-perfume,low odor detection threshold perfume ingredients, wherein said low odordetection threshold perfume ingredients may comprise less than about25%, by weight of the total neat perfume composition, or mixturesthereof, e) a perfume comprising a perfume raw material selected fromthe group consisting of 3-(4-t-butylphenyl)-2-methyl propanal,3-(4-t-butylphenyl)-propanal, 3-(4-isopropylphenyl)-2-methylprop anal,3-(3,4-methylenedioxyphenyl)-2-methylpropanal, 2,6-dimethyl-5-heptenal,α-damascone, β-damascone, δ-damascone, β-damascenone,6,7-dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone,methyl-7,3-dihydro-2H-1,5-benzodioxepine-3-one,2-[2-(4-methyl-3-cyclohexenyl-1-yl)propyl]cyclopentan-2-one,2-sec-butylcyclohexanone, β-dihydro ionone, linalool, ethyllinalool,tetrahydrolinalool, dihydromyrcenol, and mixtures thereof, f) asoftening active selected from the group consisting of polyglycerolesters, oily sugar derivatives, wax emulsions, N,N-bis(stearoyl-oxy-ethyl) N,N-dimethyl ammonium chloride,N,N-bis(tallowoyl-oxy-ethyl) N,N-dimethyl ammonium chloride,N,N-bis(stearoyl-oxy-ethyl) N-(2 hydroxyethyl) N-methyl ammoniummethylsulfate, and mixtures thereof, g) a deposition aid polymerselected from the group consisting of starch, guar, cellulose, cassia,locust bean, Konjac, Tara, galactomannan, polyDADMAC, Tapioca starch,polyTriquat, and mixtures thereof, h) a deposition aid polymer selectedfrom the group consisting of a cationic polymer having a cationic chargefrom about 0.005 meq/g to about 23 meq/g, at the pH of said composition,i) a high melting point fatty compound selected from the groupconsisting of fatty alcohols, fatty acids, fatty alcohol derivatives,fatty acid derivatives, and mixtures thereof; and j) mixtures thereof.10. The composition of claim 3, which is a laundry detergent.
 11. Thecomposition of claim 3, wherein the ratio of anionic surfactant to thesum of cationic and nonionic surfactants is from about 10:1 to about1:10.
 12. The composition of claim 11, wherein the ratio of anionicsurfactant to the sum of cationic and nonionic surfactants is from about6:1 to about 1:9.
 13. The composition of claim 12, wherein the ratio ofanionic surfactant to the sum of cationic and nonionic surfactants isfrom about 5:1 to about 1:8.
 14. The composition of claim 3, comprisinga cationic surfactant and a fabric softening active compound.
 15. Thecomposition of claim 3, wherein the composition further comprises astabilizer.